18th Annual Meeting of the Rice University Consortium

18th Annual Meeting of the Rice University Consortium

18th Annual Meeting of the Rice University Consortium on Processes in Porous Media Rice University April 21 2014 Consortium Members Baker - Hughes CESI Chemical Chevron Conoco Phillips Core Labs* Denbury Resources Ecopetrol Exxon Mobil Halliburton Huntsman Kinder Morgan Korean National Oil Co. Kuwait Oil Company * In-kind contributions Lubrizol Marathon Oil Chem* Oxy Petroleum PETRONAS PTS* Repsol Solvay Rhodia Schlumberger Shell SINOPEC Saudi Aramco SNF TIORCO Total

Faculty & Collaborators George J. Hirasaki Clarence A. Miller Walter G. Chapman Ken Cox Lisa Biswal Michael S. Wong Rafael Verduzco Francisco Vargas Scott Wellington Ed Billips (Chemistry) Jim Tour (Chemistry) Keith Johnston (UT) Quoc Nguyen (UT) Arne Graue (U. Bergen) Rouhi Farajzadeh (TU Delft, Shell) Ahmed Abdala (PI) Ali Al Sumati (PI) Maghsood Abbaszadeh (IPS) Staff, Visiting Scientist, & Post-Doc Maura Puerto (retired Exxon) Jose Lopez (PhD, Rice) Angelica Garcia (B.Sc., M.Sc., UANL) Zhen Wang (PhD, Zhejiang University) Current Ph.D. Students

Charles Conn (defended) Leyu Cui (defended) Aparna Raju Sagi Hadi ShamsiJazeyi Aarthi Muthuswamy Yongchao Zeng Luqing Qi Leo Wang Yu-Jiun (Nate) Lin Ding Li (visiting, China University of Petroleum) Gedeng (Gordon) Ruan Pengfei (Patrick) Dong Guoqing (Michael) Jian Daniel Vecchiolla Jason Mann Undergraduate Students Chang Da Paige Horton Maggie Jerome Sun Hye Kim Dongheon Lee Sha Li Tung Nguyen

Aaron Roudina Chang Tian Austin Woo Shaoyu Zhu Lisa Chiba Alina Datta-Gupta Sun Ji Yichen Liu Michael Mardock Dan Su Yu Su Naina Noorani Ramsey Padilla Jeffrey Joyce Jesus Duran Ph. D. graduates in oil & gas industry Robert Szafranski (1997), Exxon-Mobil Sho-Wei Lo (1999), BHP Billiton Dicksen Tanzil (2001), BRIDGES to Sustainability Gigi Qian Zhang (2001) Baker Hughes David Ting (2003), Shell Alejandro Pena (2003), Schlumberger, Sugarland Jason Chen (2005), Marathon Leslie Zhang (2005), Schlumberger, Houston Mark Flaum (2006 ), Schlumberger - Sugarland Wei Yan (2006), Bectel, IPS Vivek Anand (2007), Schlumberger - Sugarland Ph. D. graduates in oil & gas industry (cont.)

Shunhua Liu (2008), Oxy Gaurav Bhatnagar (2008), Shell Doris Gonzalez (2008), BP Clint Aichele (2009), Oklahoma State University Tianmin Jiang (2009), Schlumberger Francisco Vagas (2009), Rice University Arjun Kurup (2009), Schlumberger Robert Li (2011), Shell Elton Yang (2011), Chevron Richmond Michael Rauschhuber (2011), Chevron Richmond Sayantan Chatterjee (2012), Shell Neeraj Rohilla (2012), TIORCO Ph. D. graduates in oil & gas industry (cont.) Kun Ma (2013) Total Sumedh Warudkar (2013) Shell Sai Panuganti (2013) BP Charles Conn (summer, 2014) Shell Processes in Porous Media Consortium Focus Areas NMR well logging Wettability alteration & low IFT EOR Foam mobility control Emulsion separation Asphaltene deposition Gas hydrate Core competency Formation evaluation Enhanced oil recovery

Flow assurance Products Graduates Theses Preprints for publications Computer code (upon request) Department of Energy Novel CO2 Foam Concepts and Injection Schemes for Improving CO2 Sweep Efficiency in Sandstone and Carbonate Hydrocarbon Formations (2010-2014) Quoc Nguyen, UT Keith Johnston, UT Arne Graue, U. Bergen George Hirasaki, Rice Lisa Biswal, Rice Cost-share with Consortium Preparing pilot in East Seminole Department of Energy South Louisiana Enhanced Oil Recovery/ Sequestration Demonstration Project Blackhorse Energy, LLC Faculty Scott Wellington George Hirasaki Lisa Biswal Student/Staff Guoqing (Michael) Jian Maura Puerto Department of Energy Post-Combustion Carbon Dioxide Capture 2011-2014 Faculty Michael S. Wong George J.Hirasaki Ken R. Cox Ed Billips (Chemistry) PhD and Post-doc Zhen Wang (Post-Doc) Proprietary Research

National Oil Company EOR ADNOC CO2 Foam, Low IFT, & Asphaltene, with UT & PI IOC Surfactant Formulations IOCs Hydrocarbon gas (WAG) mobility control AEC Nanoparticles for low IFT Manuscripts on: Website: http://www.owlnet.rice.edu/~gjh/Consortium/ Adsorption of a Cationic Surfactant on Carbonate Minerals, by Leyu Cui (Download) Asphaltene Behavior in Crude Oil Systems, PhD thesis by Sai Panugant (Download) Polydisperse behavior of asphaltenes during precipitation, by Mohammad Tavakkoli (Download) Property Scaling Relations for Nonpolar Hydrocarbons, by Sai Panugant (Download) SAFT model for upstream asphaltene applications, by Sai Panugant (Download) PC-SAFT Characterization of Crude Oils and Asphaltene, by Sai Panuganti (Download) Tar Mat from Asphaltene Compositional Grading, by Sai Ravindra Panuganti, et al.(Download) Carbon Capture, High Pressure Stripper, by Sumedh Warudkar, et al. (Download) Carbon Capture, Low Pressure Stripper, by Sumedh Warudkar, et al. (Download) Sacrificial Agent for Surfactant Adsorption, by Hadi Shams Jazaya, et al. (Download)

Surfactant Flooding Low Salinity, Fractured Carbonate Reservoir, by Aparna Raju Sagi, et al. Estimation of Foam Parameters, Part 2, by Kun Ma, et al. Simulation of Foam Flow: Dry-Out Effect, by Kum Ma,et al. Determination of Anhydrite in Reservoirs for EOR by Jose Lopez, et al. Agenda 8:00 8:05 8:15 8:25 8:40 9:00 9:20 9:40 10:00 10:20 10:35 10:55 11:15 11:35 11:55 12:15 1:30 1:50 2:10 2:30 2:50 3:10 3:30 3:40 3:50 4:00 4:20 Welcome (George Hirasaki) Rice Energy & Environment Initiative (Charles McConnell) The NORTEX Collaboration (Arne Graue) Introduction to Consortium (George Hirasaki) Formulations for Low IFT and Strong Foam (Maura Puerto) Foam in Porous Media and Fractures (Jose Lopez Salinas)

Adsorption of Betaine (Hadi ShamsiJazeyi) Alkali / Crude Oil Phase Behavior (Ding Lei) Effect of Hardness and Cosurfactant in PO Sulfate Systems (Clarence Miller) Break Mixtures of Anionic-Cationic Surfactants (Yingcheng Li) Betaine: Anionic Surfactant Blends for Foam (Aarthi Muthuswamy) Effect of Surfactant Partition Coefficient on Foam Transport (Yongchao Zeng) CO2 Foam at Reservoir Conditions (Leyu Cui) Foam Transport in Micromodels (Charles Conn) Lunch Ultra-Low IFT with New Sulfonate-Based Nanomaterial (Michael Wong) Polymeric Nanoparticles for Hydrocarbon Detection (Gedeng (Gordon) Ruan) Bottlebrush Polymer & Surfactant for Low IFT (Luqing Qi) Partitioning of Surfactant between Phases (Aparna Raju Sagi) Asphaltene Deposition in Microfluidic Channels (Yu-Jiun (Nate) Lin) Prediction and Mitigation of Asphaltene Deposition (Francisco Vargas) Consortium on Petroleum Thermodynamics and Flow Assurance (Vargas) Tuning Chemomechanics of Well Cement (Rouzbeh Shahsavari) Rice University Water and Energy Research Center (Qilin Li) Recommendations from Consortium Members Laboratory Tour Lab Tours Micromodels EOR Formulation EOR Flooding Also Keck 207 for Verduzco polymer lab You are here Attendees Proett Mark Aramco Services Co. Quintero Lirio Baker Hughes Williams Mark Baker Hughes Zhang

Boyang Baker Hughes Zhang Ying Bayer Technology Services Germack David CESI Chemical Hill Randall CESI Chemical Lett Nathan CESI Chemical Hammond Charles CESI Chemical a FLOTEK Company Adepoju Ola Chevron Fathi Nariman Chevron Ma Xianlin Chevron

Mims Don Chevron Sayarpour Morteza Chevron Xu Josh Chevron Yang Elton Chevron Lo Wickramathilaka Grobelny Jank Parris Xie hawley Parris Vo D'Souza Mohan Mohan Sinha Stegemeier Lilian Siluni Michael Thomas Lisa Harry philip Lisa Tuan David Aruna Lavanya Somnath George L.

ConocoPhillips ConocoPhillips Core Lab Core Lab Core Lab Core Lab Core Laboratories Core Laboratories Core Laboratories Denbury ExxonMobil Upstream Research Company ExxonMobil Upstream Research Company ExxonMobil Upstream Research Company GLS Engineering, Inc. Chen Palla Qu Ye Salazar Gharbi He Chang Jackson Xiu Chen Kothamasu He Feng Nguyen Berger Sharp ZAINAL Abdul Manap Cheng Chandra Liangwei Allan Luis Ridha Peng Zen-Yu Mitchell Zongming Hung-Lung Ramya Kai Lijie Duy Paul Kip

SUZALINA Arif Azhan Halliburton Halliburton Halliburton Halliburton Huntsman Kuwait Oil Company Los Alamos National Laboratory Lubrizol Lubrizol Lubrizol Marathon Oil Company Multichem Multichem, a Halliburton Service Multi-Chem, A Halliburton Service Nalco Champion Oil Chem Technologies Oxiteno PETRONAS RESEARCH PETRONAS Research SB Attendees Cassiola Flavia Rice Cheng Yinhong Rice Univ. CHBE Ahmed Wael Rice University Al Hammadi Ali Rice University Ballal Deepti Rice University

Biswal Lisa Rice University Chapman Walter Rice University Conn Charles Rice University Cui Leyu Rice University Da Chang Rice University Ding Lei Rice University Dong Pengfei Rice University Fu Justin Rice University Garcia Angelica

Rice University Hirasaki George Rice University Jian Guoqing Rice University Liu Astron Rice University Lopez Jose Rice University Mann Jason Rice University Munday Sarah Rice University Muthuswamy Aarthi Rice University pradhan sivaram Rice University Puerto Maura

Rice University Qi Luqing Rice University Ruan Gedeng Rice University Sagi Aparna Raju Rice University ShamsiJazeyi Hadi Rice University Tian Chang Rice University Vecchiolla Daniel Rice University Wang Le Rice University wang zhen Rice University WONG

MICHAEL RICE UNIVERSITY Woo Austin Rice University Zeng Yongchao Rice University Andersen Clark Dementyev Howe Mitchell Lyashkov Li Mantilla Poteau Raney Shukla Haddix Mogri Raney Geib van Kuijk Dubey King Pretzer Southwick Mark Brian Anatoly Andrew Jonathan Victor Robert Cesar Sandrine Olina Shunahshep Grant Zen Kirk Sonja Sjoerd

Sheila Timothy Lori Jeff Schlumberger Schlumberger Schlumberger Schlumberger Schlumberger Schlumberger Technology Corp. Shell Shell Shell Shell Shell Shell Chemicals Shell Chemicals Shell E&P Shell Global Solutions Shell Global Solutions Shell Global Solutions (US) Inc. Shell Global Solutions, Inc. Shell Global Solutions, U.S. Shell Sarawak XU GUAN LI Sinopec Exploration & Production Research Institute Li Yingcheng Sinopec Shanghai Research Institute of Petrochemical Technology Yang Yuying SINOPEC Shanghai Research Institute of Petrochemical Technology Yuan Junjun SINOPEC Shanghai Research Institute of Petrochemical Technology

Zhai Xiaodong Sinopec Shanghai Research Institute of Petrochemical Technology Zhai Xiaodong Sinopec Shanghai Research Institute of Petrochemical Technology Dahanayake Manilal Solvay Ravikiran Ravi TIORCO LLC Waldman Tom TIORCO LLC Deligny Julien Total Levitt David Total Ma Kun Total morel

danielle total Mateen Khalid TOTAL E&P R&T USA ren Guangwei Total E&P R&T USA Klimenko Alexandra Total S.A, PERL Metzger Andrew Tour Lab Graue Arne University of Bergen

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